For a fixed vv and ν>0\nu>0, diffusion in direction vv is the operator

νDv2f=ν(v)2f=νi,jvivjijf.\nu D_v^2f=\nu(v\cdot\nabla)^2f =\nu\sum_{i,j}v_iv_j\partial_i\partial_jf.

The direction is constant in space; a varying vector field would also contribute derivatives of its coefficients.

Axial diffusion

For the axial direction v=ezv=e_z, the term is νz2f\nu\partial_z^2f. Under z=LzZz=L_zZ, it becomes νLz2Z2f\nu L_z^{-2}\partial_Z^2f. Comparing it with radial diffusion therefore requires the two length scales and the radial operator, including any coordinate-basis terms.