Definition

Let AA be a . A φS(A)\varphi\in S(A) is pure if it is an extreme point of the : whenever

φ=tψ+(1t)χ\varphi=t\psi+(1-t)\chi

for states ψ,χS(A)\psi,\chi\in S(A) and 0<t<10<t<1, one must have ψ=χ=φ\psi=\chi=\varphi. Thus purity means that φ\varphi admits no nontrivial convex decomposition into other states. It is a convex-geometric condition, not a continuity or nondegeneracy condition; in particular, purity does not mean normality or faithfulness.

GNS characterization

A state is pure if and only if its is irreducible. This connects extreme points of S(A)S(A) with of AA. The equivalence is a theorem, not an alternative convention for the definition Murphy, §3.3.

Standard examples

For A=C0(X)A=C_0(X), pure states are evaluations ff(x)f\mapsto f(x) at points xXx\in X; equivalently, they are the . On Mn(C)M_n(\mathbb C), pure states are φ(a)=aξ,ξ\varphi(a)=\langle a\xi,\xi\rangle for unit vectors ξ\xi, or of rank one. A density matrix of rank greater than one gives a mixed, not pure, state.

Distinctions
References
  1. Gerard J. Murphy, C-Algebras and Operator Theory*, Academic Press, 1990. DOI record. Relevant: §3.3 on pure states and irreducible GNS representations.
  2. Gert K. Pedersen, C-Algebras and Their Automorphism Groups*, 2nd ed., Academic Press, 2018. DOI record. Relevant: §3.3 on states and purity.