Susceptibility equals variance of magnetization
Finite-volume fluctuation–response identity: magnetic susceptibility is β times the magnetization variance (per volume).
Susceptibility equals variance of magnetization
Let be a finite-volume Gibbs measure on a finite region , with inverse temperature and external magnetic field coupled linearly to the total magnetization (e.g. for the Ising model ). Let
- be the partition function ,
- be the (finite-volume) pressure ,
- be the magnetization density,
- be the (finite-volume) susceptibility per site.
Statement
Assume the Hamiltonian depends on only through a term (linear field coupling). Then exists and
Equivalently,
Key hypotheses
- Finite region and a well-defined finite-volume Gibbs measure .
- External field enters the energy as (linear coupling).
- Expectations and variances in the ensemble are finite (automatic for bounded spins).
Conclusions
- since it is proportional to a variance.
- Susceptibility is a fluctuation: large magnetization fluctuations imply large response to .
- This is a concrete instance of the fluctuation–response principle .
Proof idea / significance
Differentiate with respect to . The first derivative gives , and the second derivative produces the covariance (variance) term. The identity underlies many response formulas and connects critical behavior to diverging fluctuations.