Connected correlations as derivatives of expectations
In Gibbs ensembles, derivatives with respect to conjugate parameters yield covariances (connected two-point functions) and higher cumulants.
Connected correlations as derivatives of expectations
Let be a Gibbs/ensemble measure (e.g. canonical ensemble or finite-volume Gibbs measure ) whose Hamiltonian depends on a real parameter via a linear coupling to an observable :
Let denote ensemble averages with respect to .
Statement
For any integrable observable ,
In other words,
where is the (two-point) connected correlation, i.e. the connected two-point function at the level of observables.
In particular, for the partition function (canonical or lattice ),
with variance as in variance in an ensemble .
More generally, if one introduces sources coupled to observables , then mixed partial derivatives of generate higher connected correlations (cumulants).
Key hypotheses
- The parameter enters linearly: (or, more generally, differentiably with ).
- The relevant derivatives can be passed under the integral/sum defining (automatic in finite volume with bounded observables).
- is fixed (inverse temperature).
Conclusions
- Response of to the field conjugate to is controlled by their covariance.
- Taking recovers a fluctuation identity:
- This packages many “susceptibility = fluctuation” statements, including susceptibility–variance for magnetization as a special case.