Multiple Gibbs states and spontaneous symmetry breaking
Statement (symmetry breaking from phase coexistence)
Consider a lattice spin system with a global symmetry (e.g. spin-flip symmetry in the Ising model at external field ). Suppose that at some parameter values (typically low temperature) there exist at least two distinct infinite-volume Gibbs measures for the same specification.
Then the symmetry is spontaneously broken in the sense that there exist distinct Gibbs measures such that a symmetry-related order parameter takes different values in these states (e.g. magnetization differs).
For the ferromagnetic Ising model in dimension , the Peierls argument implies that for sufficiently large (low temperature) there are at least two distinct translation-invariant Gibbs measures and obtained as limits with and boundary conditions, and they satisfy
- (spin-flip symmetry),
- (nonzero spontaneous magnetization).
Key hypotheses
- A symmetric specification (e.g. invariance under global spin flip when ).
- Existence of multiple Gibbs measures (phase coexistence), typically shown via Peierls argument or other low-temperature methods.
- An order parameter odd under the symmetry (e.g. single-site spin ).
Conclusions
- Nonuniqueness of Gibbs states produces physically distinct macroscopic phases.
- The symmetry is not realized in each pure phase (each extremal state), but is restored by mixtures: the symmetric state can be formed as , which is Gibbs but not extremal.
Cross-links (definitions and supporting results)
- Ising model
- infinite-volume Gibbs measures , extremal (pure) Gibbs measures
- phase transition via Gibbs nonuniqueness
- uniqueness implies no phase transition
- this corollary
Proof idea / significance
In symmetric models, if two distinct infinite-volume Gibbs measures exist and the symmetry maps Gibbs measures to Gibbs measures, then applying the symmetry to one state produces another. In the Ising case at , spin flip maps a -magnetized state to a -magnetized state. The Peierls argument constructs low-temperature stability of (and ) boundary conditions, producing distinct limiting Gibbs measures with opposite magnetizations. This is the canonical mechanism for spontaneous symmetry breaking in equilibrium statistical mechanics.