Lattice partition function
Fix a finite region of the lattice (see finite boxes in a lattice ) and a single-site spin space with a reference (a priori) measure on . A spin configuration on is an element , and a boundary condition is a configuration on the complement .
Given an inverse temperature (see inverse temperature ) and a finite-volume lattice Hamiltonian , the finite-volume lattice partition function is
where is the product measure on induced by (see product measure ).
If is finite (e.g. the Ising single-spin set ), the integral reduces to a finite sum over .
This object is the lattice analogue of the canonical partition function .
Key properties
Normalization for Gibbs weights. The partition function is the normalizing constant for the finite-volume Gibbs measure :
Boundary dependence. In general depends on the boundary condition ; for finite-range interactions the dependence is through spins near the boundary of .
Generates thermodynamics. Derivatives of with respect to parameters in (e.g. a magnetic field coupling ) produce finite-volume expectations and fluctuations (see ensemble averages ).
Physical interpretation
is the weighted “count” of microstates in compatible with an environment , with each configuration weighted by the Boltzmann factor . Its logarithm controls the finite-volume free energy and leads directly to the lattice pressure and its thermodynamic limit.