Statement

There is an isomorphism of

Spin(6)SU(4).\operatorname{Spin}(6)\cong SU(4).

Infinitesimally it gives an isomorphism of real

spin(6)so(6)su(4),\mathfrak{spin}(6)\cong\mathfrak{so}(6) \cong\mathfrak{su}(4),

and after complexification it is the exceptional root-system identification D3=A3D_3=A_3:

so6(C)sl4(C).\mathfrak{so}_6(\mathbb C)\cong\mathfrak{sl}_4(\mathbb C).
Corresponding representations

Under a choice of this isomorphism, the two complex of Spin(6)\operatorname{Spin}(6) correspond to the defining representation of SU(4)SU(4) on C4\mathbb C^4 and its dual:

Δ+C4,Δ(C4).\Delta^+\leftrightarrow\mathbb C^4, \qquad \Delta^-\leftrightarrow(\mathbb C^4)^*.

Interchanging chirality interchanges the two right-hand representations.

The complexification of the six-dimensional corresponds to the second :

C6Λ2C4.\mathbb C^6\cong\Lambda^2\mathbb C^4.

Because SU(4)SU(4) preserves a Hermitian form and a complex volume form on C4\mathbb C^4, Λ2C4\Lambda^2\mathbb C^4 carries an invariant real structure. Its fixed real subspace has dimension six and gives the homomorphism

SU(4)SO(6).SU(4)\longrightarrow SO(6).

Its kernel is {±I}\{\pm I\}, so it is the spin double covering.

Why the group isomorphism follows

The compact groups Spin(6)\operatorname{Spin}(6) and SU(4)SU(4) are both connected and simply connected, and their Lie algebras are isomorphic. A Lie-algebra isomorphism between connected integrates uniquely to a Lie-group isomorphism.

This is stronger than SO(6)SU(4)SO(6)\cong SU(4): that latter statement is false. Instead,

SO(6)SU(4)/{±I}.SO(6)\cong SU(4)/\{\pm I\}.

The remaining central elements ±iI\pm iI act nontrivially in the vector-covering construction before quotienting by the appropriate kernel.

Convention warning

No preferred isomorphism singles out which of Δ+\Delta^+ or Δ\Delta^- is C4\mathbb C^4. Orientation reversal on the orthogonal side and complex conjugation on the unitary side exchange the two choices.

References
  1. H. Blaine Lawson Jr. and Marie-Louise Michelsohn, Spin Geometry, Princeton University Press, 1989, Chapter I, §5. Publisher record.
  2. William Fulton and Joe Harris, Representation Theory: A First Course, Springer, 1991, §§19–20. Publisher record.