Let GG be a with g=TeG\mathfrak{g}=T_eG. For each XgX\in\mathfrak{g}, let XLX^L denote the left-invariant vector field on GG determined by XX (so XeL=XX^L_e=X). Let γX:RG\gamma_X:\mathbb R\to G be the unique solution of γX(t)=XγX(t)L\gamma_X\prime(t)=X^L_{\gamma_X(t)}, γX(0)=e\gamma_X(0)=e. A left-invariant vector field is complete, so this curve is defined for every real tt.

The (Lie group) exponential map is

exp:gG,exp(X)=γX(1).\exp:\mathfrak{g}\to G,\qquad \exp(X)=\gamma_X(1).
Local properties

It satisfies exp(0)=e\exp(0)=e and its differential at 00 is the identity map on g\mathfrak{g}. Moreover, exp\exp is a local diffeomorphism near 0g0\in\mathfrak{g} (so it provides coordinates near the identity in GG).

Examples
  1. Matrix groups. For GGL(n,R)G\subset \mathrm{GL}(n,\mathbb{R}) a matrix Lie group, exp\exp agrees with the matrix exponential Xk01k!XkX\mapsto \sum_{k\ge0}\frac{1}{k!}X^k (and lands in GG when XgX\in\mathfrak{g}).
  2. Additive group. For G=RnG=\mathbb{R}^n under addition, gRn\mathfrak{g}\cong\mathbb{R}^n and exp\exp is the identity map.
  3. Circle group. For G=S1CG=S^1\subset\mathbb{C}, gR\mathfrak{g}\cong\mathbb{R} and exp(t)=eit\exp(t)=e^{it} (up to the chosen identification of g\mathfrak{g} with R\mathbb{R}).