Fix an U={Ui}\mathcal U=\{U_i\} and a Lie group GG. The Čech cocycle groupoid has g={gij}g=\{g_{ij}\} as objects. A morphism ggg\to g' is a family of smooth maps hi:UiGh_i:U_i\to G such that

gij=hi1gijhjg'_{ij}=h_i^{-1}g_{ij}h_j

on every overlap. If h:ggh:g\to g' and k:ggk:g'\to g'', their composite khk\circ h is represented by (hiki)i(h_i k_i)_i. The identity has every component ee, and the inverse of hh has components hi1h_i^{-1}. Associativity follows from group multiplication.

Why it is a groupoid

Every morphism is invertible because each hih_i is group-valued. Passing to isomorphism classes gives the of nonabelian Čech H1H^1, while retaining the groupoid also retains the automorphisms of each cocycle. For a cocycle defining a principal bundle, these automorphisms correspond to its gauge transformations.

Relation to bundle classification

The gluing construction identifies this groupoid with the groupoid of principal GG-bundles trivializable over U\mathcal U, with all bundle isomorphisms; choosing local trivializations gives the cocycle presentation. Refining covers gives the cover-independent descent description.

References
  1. Jean-Luc Brylinski, Loop Spaces, Characteristic Classes and Geometric Quantization, Birkhäuser, 1993. DOI record. Relevant: Čech cocycles, descent, and bundle classification.